1,1,3,3-Tetramethyldisiloxane
- CAS No.
- 3277-26-7
- Chemical Name:
- 1,1,3,3-Tetramethyldisiloxane
- Synonyms
- TMDSO;TETRAMETHYLDISILOXANE;TMDO;(Me2HSi)2O;Dimethylsilyl ether;Disiloxane, 1,1,3,3-tetramethyl-;5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2-(trifluoromethyl)pyridine;DK740;DK741;DK265
- CBNumber:
- CB5355451
- Molecular Formula:
- C4H14OSi2
- Molecular Weight:
- 134.32
- MDL Number:
- MFCD00008256
- MOL File:
- 3277-26-7.mol
- MSDS File:
- SDS
Melting point | <-78°C |
---|---|
Boiling point | 70-71 °C (lit.) |
Density | 0.76 g/mL at 25 °C (lit.) |
vapor pressure | 250 hPa (20 °C) |
refractive index |
n |
Flash point | 14 °F |
storage temp. | Store at <= 20°C. |
solubility | soluble in Chloroform |
pka | 11.9[at 20 ℃] |
form | liquid |
color | colorless |
Specific Gravity | 0.757 |
explosive limit | 0.8-62.9%(V) |
Viscosity | 0.7mm2/s |
Water Solubility | DECOMPOSES |
Sensitive | Moisture Sensitive |
Hydrolytic Sensitivity | 3: reacts with aqueous base |
BRN | 1733364 |
InChIKey | NVYQDQZEMGUESH-UHFFFAOYSA-N |
LogP | -0.38-4.5 at 20-25℃ |
CAS DataBase Reference | 3277-26-7(CAS DataBase Reference) |
EWG's Food Scores | 1 |
NIST Chemistry Reference | ((CH3)2SiH)2O(3277-26-7) |
EPA Substance Registry System | Disiloxane, 1,1,3,3-tetramethyl- (3277-26-7) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS02 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H225 | |||||||||
Precautionary statements | P210-P233-P240-P241-P242-P243 | |||||||||
Hazard Codes | F | |||||||||
Risk Statements | 11-36/37/38-16 | |||||||||
Safety Statements | 16-26-36-9-33-29 | |||||||||
RIDADR | UN 2924 3/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | JN1000000 | |||||||||
F | 10-21 | |||||||||
Autoignition Temperature | 240 °C | |||||||||
TSCA | Yes | |||||||||
HazardClass | 3 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29310095 | |||||||||
NFPA 704 |
|
1,1,3,3-Tetramethyldisiloxane price More Price(30)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 235733 | 1,1,3,3-Tetramethyldisiloxane 97% | 3277-26-7 | 25g | $36.5 | 2024-03-01 | Buy |
Sigma-Aldrich | 235733 | 1,1,3,3-Tetramethyldisiloxane 97% | 3277-26-7 | 100g | $121 | 2024-03-01 | Buy |
TCI Chemical | T1437 | 1,1,3,3-Tetramethyldisiloxane >97.0%(GC) | 3277-26-7 | 25mL | $26 | 2024-03-01 | Buy |
TCI Chemical | T1437 | 1,1,3,3-Tetramethyldisiloxane >97.0%(GC) | 3277-26-7 | 250mL | $142 | 2024-03-01 | Buy |
Alfa Aesar | B23697 | 1,1,3,3-Tetramethyldisiloxane, 97% | 3277-26-7 | 25g | $38.65 | 2024-03-01 | Buy |
1,1,3,3-Tetramethyldisiloxane Chemical Properties,Uses,Production
Description
1,1,3,3-Tetramethyldisiloxane is soluble in many organic solvents, such as aromatic hydrocarbon and petroleum hydrocarbons, and so on. This product is a kind of widely used organic silicon intermediates, and usually be used as organic silicon blocking agent. Due to containing reactive Si-H groups in the molecular structure, it can be used in the synthesis of copolymer macromolecule by hydrosilylation. The synthesis of copolymer macromolecule can be made into a series of reactive silicone oil.
Chemical Properties
Colorless or yellowish transparent liquid
Uses
1, 1, 3, 3-Tetramethyldisiloxane is a kind of siloxane derivative, and can be used as a monomer for the preparation of silicone polymers or silicone resins. It is used as an intermediate for preparing other organosilicon compounds. It is also used in non-aqueous polymer preparation as well as a laboratory reagent. In organic synthesis, it finds an application as an effective reducing agent in platinum-catalyzed reduction of carboxamides to amines as well as in the Au/TiO2-catalyzed hydrosilylation of carbonyl compounds (e.g., reduction of aldehydes or ketones) relative to monohydrosilanes. It can also enable a direct bromination of carboxylic acids in the presence of indium bromide (InBr3) as catalyst.
Uses
1. Synthesis of polysiloxane containing faculties end groups.
2. Can be used for the preparation of high performance organic silicone surfactants.
3. Applicable to the production of many products, such as addition silicon rubber, silica gel, Hydrogenpolysiloxane and plastic, resin modifier, dendrite polymer special additives, etc.
Uses
1,1,3,3-Tetramethyldisiloxane is used as a monomer in the production of silicone polymers or silicone resins. It is used as a precursor to prepare other organosilicon compounds. It is also utilized in non-aqueous polymer preparation as well as a laboratory reagent.
Flammability and Explosibility
Highly flammable
Purification Methods
1,Possible impurity is 1,1,5,5-tetramethyl-3-trimethylsiloxytrisiloxane b 154-155o/733mm. Fractionate it, collect fractions boiling below 80o and re-fractionate it. Its purity can be analysed by alkaline hydrolysis and measuring the volume of H2 liberated followed by gravimetric estimation of silica in the hydrolysate. It is unchanged when stored in glass containers in the absence of moisture for 2-3 weeks. Small amounts of H2 are liberated on long storage. Care should be taken when opening a container due to pressure developed. [Speier et al. J Am Chem Soc 79 974 1958, Emeléus & Smythe J Chem Soc 609 1958, IR: Kriegsmann Z Anorg Chem 299 78 1959, Beilstein 4 IV 3991.]
References
https://www.alfa.com/en/catalog/B23697/
http://www.organic-chemistry.org/chemicals/reductions/tetramethyldisiloxane-TMDSO.shtm
https://www.infona.pl/resource/bwmeta1.element.elsevier-722236cc-df38-37aa-bbed-029ec07d525f
1,1,3,3-Tetramethyldisiloxane Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
SIMAGCHEM CORP | +86-13806087780 | sale@simagchem.com | China | 17367 | 58 |
CD Chemical Group Limited | +8615986615575 | info@codchem.com | China | 20356 | 58 |
Wuhan Kemi-Works Chemical Co., Ltd. | +86-2785736489 +8618171418573 | sales@kemiworks.com | China | 704 | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | forrest.lee@dakenchem.com | China | 15956 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12471 | 58 |
Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 6008 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
Jiangxi New jiayi New Materials Co., Ltd. | 15988280056 | mina@xjysi.com | CHINA | 27 | 55 |
Hangzhou Bayee Chemical Co., Ltd. | 0086-571-86990109 | rachelhoo@bayeechem.com | China | 104 | 55 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21689 | 55 |
Related articles
- 1,1,3,3-Tetramethyldisiloxane: A Versatile Organosilane for Safe and Selective Organic Synthesis Processes
- 1,1,3,3-Tetramethyldisiloxane is a versatile organosilane with reactivity, and safety in organic synthesis, notably as a reduc....
- Apr 28,2024
- 1,1,3,3-Tetramethyldisiloxane: A Versatile Compound for Efficient Chemical Transformations and Synthesis
- 1,1,3,3-Tetramethyldisiloxanecan be synthesized through hydrosilylation reactions and is a versatile compound used as reactant....
- Dec 26,2023
- 1,1,3,3-Tetramethyldisiloxane: properties, applications in battery production and safety
- 1,1,3,3-Tetramethyldisiloxane enhances battery performance and is compatible with various materials. Follow safety precautions....
- Jul 12,2023
View Lastest Price from 1,1,3,3-Tetramethyldisiloxane manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2023-11-16 | 1,1,3,3-Tetramethyldisiloxane
3277-26-7
|
US $50.00-3.00 / kg | 1kg | 0.99 | 20 tons | Hebei Yanxi Chemical Co., Ltd. | ||
2023-11-01 | 1,1,3,3-Tetramethyldisiloxane
3277-26-7
|
US $0.00-0.00 / kg | 0.1kg | 99.0%min | 20000kg | Hangzhou ICH Biofarm Co., Ltd | ||
2023-09-08 | 1,1,3,3-Tetramethyldisiloxane
3277-26-7
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd |
- 1,1,3,3-Tetramethyldisiloxane
3277-26-7
- US $50.00-3.00 / kg
- 0.99
- Hebei Yanxi Chemical Co., Ltd.
- 1,1,3,3-Tetramethyldisiloxane
3277-26-7
- US $0.00-0.00 / kg
- 99.0%min
- Hangzhou ICH Biofarm Co., Ltd
- 1,1,3,3-Tetramethyldisiloxane
3277-26-7
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
3277-26-7(1,1,3,3-Tetramethyldisiloxane)Related Search:
1of4